Tellurium-containing Polymers: Recent Developments and Trends

Yiheng Dai, Jun Guan, Shenghan Zhang, Shuojiong Pan, Banruo Xianyu, Zhuoxin Ge, Jinyan Si, Chaowei He, Huaping Xu Prog. Polym. Sci.; 2023, 141, 101678. Significant progresses have been made in tellurium-containing polymers over the past decades. Just like other heteroatom-containing polymers, tellurium-containing polymers exhibit several unique properties and promising applications. However, unlike elements such as boron, silicon, sulfur and so on, tellurium in polymers remains a fresh perspective for many researchers. In this review, we shall illustrate the diversification of tellurium-...
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Joint Group Meeting between Prof. Huaping Xu’s Group and Prof. Yi Cao’s Group

联合组会
On March 24th, a joint group meeting was held between Prof. Huaping Xu’s Group from Tsinghua University, Prof. Yi Cao’s Group from Nanjing University and Prof. Fengwei Huo's Group from Nanjing Tech University. The meeting was chaired by Dr. Ju Guan (Xu' Group) and Dr. Fanchen Meng, consisting of twelve reports totally from three groups. Mr. Yizheng Tan, Mr. Shuojiong Pan, Mr. Peng Zhao and Mr. Yiheng Dai From our group made the oral presentation respectively. At the end of the meeting,  Prof. Huaping Xu made a summary and outlook.
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A nanotherapeutic strategy to reverse NK cell exhaustion

Shuojiong Pan, Jun Guan, Banruo Xianyu, Yizheng Tan, Tianyu Li, and Huaping Xu Adv. Mater.; 2023, 23, 2211370. As a specialized immune effector cell, natural killer (NK) cells play a very important role in immunotherapy, but tumor immunosuppression caused by abnormal expression of cancer cells seriously weakens its therapeutic effect and leads to exhaustion. Here, we developed a self-assembled selenium containing nanoparticles (NPs) composed of Cetuximab, C5SeSeC5 and inhibitor LY345899 to reverse NK cell exhaustion. The obtained NPs can target EGFR on the surface of cancer cells and locat...
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Mechanochemistry of dynamic chalcogen-containing polymers: a minireview

Muqing Cao, Yizheng Tan and Huaping Xu New Journal of Chemistry; 2023, 47, 5582. In recent years, mechanochemistry of polymers, which means the reactivity of polymers under mechanical stimuli, has been widely studied and greatly developed. Among various kinds of mechano-responsive polymers, dynamic chalcogen-containing polymers have attracted more attention due to their sensitive responsiveness and precise biofunction. In this perspective, we provide an overview of mechanochemistry of dynamic chalcogen-containing polymers, including both fundamental mechanochemistry and applications. Particu...
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Dynamic Fluorescent Patterning Based on Visible-Light-Responsive Diselenide Metathesis

Jinyan Si, Peng Zhao, Jun Guan, Shaobo Ji and Huaping xu Langmuir; 2022, 38, 13272 A diselenide bond, as a dynamic covalent bond, is a versatile tool to construct smart interfaces, which can respond to visible light. In this work, we used microcontact printing (μCP) to construct diselenide patterns on quartz substrates. Fluorescent patterns were obtained on the modified surfaces via the visible-light-induced diselenide metathesis reaction, which allowed the patterning process to be fast, dynamically erasable, and compatible with different fluorescent molecules including rhodamine B and b...
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