The synthesis and performance exploration of new polymer materials play a crucial role in advancing both fundamental scientific research and engineering applications. In 2010, we first reported the selenium-containing polymers with redox dual responsiveness, significantly contributing to the development of Se-containing polymers. In 2021, we prepared polytelluoxane in cells, an inorganic main-chain polymer composed entirely of VI group elements, for the first time. This discovery of polytelluoxanes bridges the gap between inorganic oxides and organic polymers. Moving forward, we plan to design...